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Synthesis and Peptide-binding Properties of a Luminescent Pyrimidine Zinc(II) Complex

Li, X., Miltschitzky, S., Grauer, A., Michlová, V. and König, B. (2006) Synthesis and Peptide-binding Properties of a Luminescent Pyrimidine Zinc(II) Complex. Tetrahedron 62, 12191 - 12196.

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The synthesis and peptide-binding properties of a Zn(II)nitrilotriacetate complex substituted with pyrimidine hydrazine amides are reported. The metal complex provides millimolar binding affinity in aqueous buffer to peptides bearing N-terminal His. The pyrimidine heterocycles intermolecularly interact with the bound peptide and quench the emission of nearby Trp residues by energy transfer.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
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Keywords:Metal complex; Peptide binding; Histidine; Luminescence; Pyrimidine
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:6272
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