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Synthesis and Structure of 1,4-Dipiperazino Benzenes - Chiral Terphenyl-type Peptide

Maity, P. ; König, B.



Abstract

The terphenyl structure has been proven to be an ideal scaffold mimicking side-chain functionalities of peptidic alpha-helices. The synthesis of 1,4-dipiperazino benzenes, using stepwise transition metal-catalyzed N-arylation of chiral piperazines to a central benzene core is reported. The structure determination by X-ray crystallography reveals a geometrical arrangement of the hydrophobic side ...

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