Krienke, Hartmut ; Ahn-Ercan, Gudrun ; Maurer, Alexander
Alternative Links zum Volltext:DOIVerlag
| Dokumentenart: | Artikel |
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| Titel eines Journals oder einer Zeitschrift: | Zeitschrift für Physikalische Chemie |
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| Verlag: | OLDENBOURG VERLAG |
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| Ort der Veröffentlichung: | MUNICH |
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| Band: | 227 |
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| Nummer des Zeitschriftenheftes oder des Kapitels: | 2-3 |
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| Seitenbereich: | S. 285-302 |
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| Datum: | 2013 |
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| Institutionen: | Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie |
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| Identifikationsnummer: | | Wert | Typ |
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| 10.1524/zpch.2013.0323 | DOI |
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| Stichwörter / Keywords: | WATER+1,4-DIOXANE MIXTURES; 1,4-DIOXANE-WATER MIXTURES; CONDUCTANCE; APPROXIMATION; 35-DEGREES-C; MODELS; Dioxane-Water Mixtures; Transport Properties; Electrolytes; Conductance |
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| Dewey-Dezimal-Klassifikation: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
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| Status: | Veröffentlicht |
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| Begutachtet: | Ja, diese Version wurde begutachtet |
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| An der Universität Regensburg entstanden: | Ja |
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| Dokumenten-ID: | 62944 |
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Zusammenfassung
Theoretical calculations of the conductivity of sodium chloride in water + 1,4-dioxane mixtures are presented and compared with experimental measurements. The method of direct correlation force in the framework of the interionic theory is used for the calculation of transport properties in connection with the associative mean spherical approximation (AMSA). The effective interactions between ions ...
Zusammenfassung
Theoretical calculations of the conductivity of sodium chloride in water + 1,4-dioxane mixtures are presented and compared with experimental measurements. The method of direct correlation force in the framework of the interionic theory is used for the calculation of transport properties in connection with the associative mean spherical approximation (AMSA). The effective interactions between ions in solutions are derived with the help of Monte Carlo calculations on the Born-Oppenheimer level. This work is based on earlier studies on structure of dioxane + water mixtures and the solvation of ions in it.
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