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Facile synthesis of 6-aryl-3-pyridyl-1,2,4-triazines as a key step towards highly fluorescent 5-substituted bipyridines and their Zn(II) and Ru(II)complexes

Kozhevnikov, V. N. ; Shabunina, O. V. ; Kopchuk, D. S. ; Ustinova, M. M. ; König, Burkhard ; Kozhevnikow, D. N.


A wide series of substituted bipyridines were obtained through the synthesis of 1,2,4-triazines and their aza Diels–Alder reactions. The reported method facilitates the synthesis of functionally diverse bipyridines that provides fine-tuning of photophysical properties of new ligands and their Zn(II) and Ru(II) complexes. Some of substituted bipyridines exhibit ‘off–on’ fluorescence response toward Zn2+ cations.

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