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Luminescent ruthenium probe for the determination of acetyl phosphate in complex biological matrices

Steiner, Mark-Steven ; Duerkop, Axel



Zusammenfassung

The first probe for the fluorogenic determination of acetyl phosphate (AcP), (bpy)(2)Ru(1,10-phenanthroline- 5,6-dione dioxime) (RuPDO), was prepared and its reaction with AcP was studied in detail. The emission of the weakly luminescent RuPDO is red shifted and strongly enhanced upon reaction with AcP in the presence of metal cations like Zn2+ or Cu2+. The reaction occurs within 60 min ...

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