Zusammenfassung
The formation of coordination polymers from copper(I) bromide and P4S3 a potentially tetradentate P donor bridging ligand was studied Whereas (P4S3)(3)(CuBr)(7) (1) formed in excellent yield, (P4S3)(CuBr)(3) (2) and (P4S3)(CuBr) (3) crystallized as mixtures The new compounds were characterized by X-ray crystallography and solid state P-31 MAS NMR spectroscopy The structure of 1 consists of a 3D ...
Zusammenfassung
The formation of coordination polymers from copper(I) bromide and P4S3 a potentially tetradentate P donor bridging ligand was studied Whereas (P4S3)(3)(CuBr)(7) (1) formed in excellent yield, (P4S3)(CuBr)(3) (2) and (P4S3)(CuBr) (3) crystallized as mixtures The new compounds were characterized by X-ray crystallography and solid state P-31 MAS NMR spectroscopy The structure of 1 consists of a 3D network of cylindrical (CuBr)(n) columns castellated (CuBr)(n) chains and diatomic CuBr units These building blocks are linked by tetradentate P4S3 molecules The structure of 2 comprises undulated (CuBr) layers which are intra and interlayer linked by tridentate P4S3 molecules Compound 3 is a one dimensional polymer composed of four membered Cu2Br2 rings which are bridged by the P-3 bases of two P4S3 molecules
Altmetric