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Synthesis And Crystal Structures Of The Polygermanide Ammoniates K4Ge9 · 9 NH3, Rb4Ge9 · 5 NH3 And Cs6Ge18 · 4 NH3

Suchentrunk, Christof ; Daniels, Jörg ; Somer, Mehmet ; Carrillo-Cabrera, Wilder ; Korber, Nikolaus



Zusammenfassung

The new compounds K4Ge9 center dot 9 NH3 and Rb4Ge9 center dot 5 NH3 were prepared by the extraction of K4Ge9 and Rb4Ge9 with liquid ammonia and characterized by low temperature X-ray structure analysis. They both contain monocapped square antiprismatic Ge-9(4-) anions. Cs6Ge18 center dot 4 NH3 was prepared by the extraction of K2Cs2Ge9 with liquid ammonia in the presence of [(Bu)(3)MeN](Br2I) as ...

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