Zusammenfassung
Four different diatom species (Chaetoceros debilis, Chaetoceros didymum, Cylindrotheca fusiformis, Nitzschia angularis) were studied by solid-state Si-29 MAS NMR spectroscopy. To determine the Q(2):Q(3):Q(4) ratios in the biosilica deposits of the diatoms, quantitative 29Si MAS NMR experiments were performed. This analysis did not reveal any differences regarding the molecular architecture of the ...
Zusammenfassung
Four different diatom species (Chaetoceros debilis, Chaetoceros didymum, Cylindrotheca fusiformis, Nitzschia angularis) were studied by solid-state Si-29 MAS NMR spectroscopy. To determine the Q(2):Q(3):Q(4) ratios in the biosilica deposits of the diatoms, quantitative 29Si MAS NMR experiments were performed. This analysis did not reveal any differences regarding the molecular architecture of the silica (i.e. the degree of condensation of the SiOH units (2 equivalent toSiOH --> equivalent toSi-O-Siequivalent to + H2O)) from the different diatom species. However, complete cells showed significantly smaller Q(4):Q(3) ratios (1.8-1.9) than extracted cell walls (2.5-2.8), indicating the existence of intracellular pools of less condensed silica.
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