Synthesis and spectroscopic properties of (oxytetracycline)tricarbonylrhenium(I) chloride

Zusammenfassung

The complex (OTC)Re-1(CO)(3)Cl, with OTC = oxytetracycline, has been prepared and characterized by elemental analysis, ESI-MS, IR and UV-Vis spectroscopy. The complex. which contains OTC as a bidentate ligand, shows an OTC intraligand fluorescence at lambda(max) = 570 nm with Phi = 2 x 10(-3) at lambda(exc) = 390 nm. (C) 2002 Elsevier Science B.V. All rights reserved.