Zusammenfassung
The complex Re(o-phan) (CO)(3)Cl is used as a photolyase model. The phosphorescence of the complex is quenched by the 1,3-dimethyluracil cyclobutane dimer with k(q)=5.4 X 10(7) M-1 s(-1). The quenching is accompanied by the cleavage of the dimer. However, this sensitized photolysis cannot be driven very far because the regenerated monomer quenches the triplet of the complex more efficiently (k(q) ...
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