Nucleophilic Functionalization of a Cationic Pentaphosphole Complex–A Systematic Study of Reactivity

URN to cite this document:: urn:nbn:de:bvb:355-epub-747531
DOI to cite this document:: 10.5283/epub.74753

Widmann, Maximilian ; Riesinger, Christoph

; Timoshkin, Alexey Y. ; Blank, Philip M. ; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 30 Jan 2025 05:57

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Abstract

The systematic nucleophilic functionalization of the cationic pentaphosphole ligand complex [Cp*Fe(η4-P5Me)][OTf] (A) with group 16/17 nucleophiles is reported. This method represents a highly reliable and versatile strategy for the design of novel transition-metal complexes featuring twofold substituted end-deck cyclo-P5 ligands, bearing unprecedented hetero-element substituents. By the reaction ...