Synthesis and Redox Chemistry of Co3E4 (E=P, As) Clusters

URN to cite this document:: urn:nbn:de:bvb:355-epub-747541
DOI to cite this document:: 10.5283/epub.74754

Piesch, Martin ; Dinauer, Sabrina B. ; Riesinger, Christoph

; Balázs, Gábor

; Scheer, Manfred

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 30 Jan 2025 06:21

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Abstract

The synthesis of the cluster complexes [(Cp’’’Co)3(μ3,η2:η2:η2-E3)(μ3-E)] (E=P (3), As (4)) starting from the anionic triple-decker complexes [K(18cr6)(dme)2][(Cp’’’Co)2(μ,η4:η4-E4)] (E=P (1), As (2)) by electrophilic quenching with the Co dimer [(Cp’’’CoCl)2] is reported. Both complexes show a distinct redox chemistry, which was first investigated by cyclic voltammetry. Subsequently, the ...