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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-747712
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.74771
Zusammenfassung
Free ions in organic solvents of low polarity would be valuable tools for the activation of low-reactivity substrates. However, the formation of unreactive ion pairs at concentrations relevant for synthesis has prevented the success of this concept so far. On the example of highly nucleophilic pyridinamide phosphonium salts in dichloromethane, we show that asymmetric aggregation offers a solution ...
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