Polyphosphorus Ligand Complexes of Coinage Metals for Multiple Capturing of Intact P4 Tetrahedra

URN to cite this document:: urn:nbn:de:bvb:355-epub-766494
DOI to cite this document:: 10.5283/epub.76649

Göschl, Claudia ; Peresypkina, Eugenia ; Hiltl, Barbara ; Virovets, Alexander V. ; Balazs, Gabor ; Scheer, Manfred

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Date of publication of this fulltext: 08 May 2025 04:35

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Abstract

Two- and three-component self-assembly reactions of [CpRFe(η5-P5)] (CpR = C5(CH3)5 (Cp*, 1a), C5(4-EtC6H4)5) (CpPEt, 1b)) with the coinage metal salts [Cu(CH3CN)4][SbF6] or AgSbF6 were investigated to study the prerequisites for the potential coordination of white phosphorus by using a sterically encumbered CpR ligand and noncoordinating anions. In the self-assembly reactions with white ...