Trigonal Bipyramidal Clusters [Tl5]7−: Synthesis and Characterization of the Zintl Phase K7−xAxTl5 (A = Rb, Cs; 0 < x ≤ 2.35)

URN to cite this document:: urn:nbn:de:bvb:355-epub-780706
DOI to cite this document:: 10.5283/epub.78070

Schwinghammer, Vanessa F. ; Kovářík, Tomáš ; Shenderovich, Ilya G.

; Minár, Ján ; Gärtner, Stefanie

License: Creative Commons Attribution 4.0
PDF
Early View
(2MB)

Date of publication of this fulltext: 18 Nov 2025 06:40

Alternative links to fulltext:DOI Publisher

This publication is part of the DEAL contract with Wiley.

Details

Preview: Early View

Export bibliographical data

Abstract

In alkali metal thallides, a huge variety of thallium clusters can be realized, which are surrounded only by alkali metals. In most cases, different cluster types are present in the crystal structures at the same time. One example is the [Tl5]7− trigonal bipyramid, which has only been observed beside [Tl9]9−, [Tl4]8−, [Tl3]7−, [Tl]5−, or [Tl8Cd3]10−. In the new ternary alkali metal thallide phase ...