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Paulo Eduardo, de Faria Junior

Generalized many-body exciton g-factors: magnetic hybridization and non-monotonic Rydberg series in monolayer WSe2

Paulo Eduardo, de Faria Junior (2025) Generalized many-body exciton g-factors: magnetic hybridization and non-monotonic Rydberg series in monolayer WSe2. arXiv. (In Press)

Date of publication of this fulltext: 12 Nov 2025 15:46
Article
DOI to cite this document: 10.5283/epub.78132


Abstract

Magneto-optics of low dimensional semiconductors, such as monolayer transition metal dichalcogenides, offers a vast playground for exploring complex quantum phenomena. However, current ab initio approaches fail to capture important experimental observations related to brightening of excitonic levels and their g-factor dependence. Here, we develop a robust and general first principles framework ...

Magneto-optics of low dimensional semiconductors, such as monolayer transition metal dichalcogenides, offers a vast playground for exploring complex quantum phenomena. However, current ab initio approaches fail to capture important experimental observations related to brightening of excitonic levels and their g-factor dependence. Here, we develop a robust and general first principles framework for many-body exciton g-factors by incorporating off-diagonal terms for the spin and orbital angular momenta of single-particle bands and many-body states for magnetic fields pointing in arbitrary spatial directions. We implement our framework using many-body perturbation theory via the GW-Bethe-Salpeter equation (BSE) and supplement our analysis with robust symmetry-based models, establishing a fruitful synergy between many-body GW-BSE and group theory. Focusing on the archetypal monolayer WSe_2, we accurately reproduce the known results of the low-energy excitons including the Zeeman splitting and the dark/grey exciton brightening. Furthermore, our theory naturally reveals fundamental physical mechanisms of magnetic-field hybridization of higher-energy excitons (s- and p-like) and resolves the long-standing puzzle of the experimentally measured non-monotonic Rydberg series (1s-4s) of exciton g-factors. Our framework offers a comprehensive approach to investigate, rationalize, and predict the non-trivial interplay between magnetic fields, angular momenta, and many-body exciton physics in van der Waals systems.



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Details

Item typeArticle
Journal or Publication TitlearXiv
Open Access Type:OA-Version in anderem Repositorium
Date2 June 2025
InstitutionsPhysics > Institute of Theroretical Physics > Chair Professor Richter > Group Jaroslav Fabian
Projects
Funded by: Deutsche Forschungsgemeinschaft (DFG) (314695032)
Identification Number
ValueType
2505.18468arXiv ID
KeywordsSubjects: Mesoscale and Nanoscale Physics (cond-mat.mes-hall); Materials Science (cond-mat.mtrl-sci)
Dewey Decimal Classification500 Science > 530 Physics
StatusIn Press
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-781329
Item ID78132

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