A New Thallide Auride Double Salt: Cs3.4K4.6[Au][Tl7] Featuring [Tl7]7– Zintl Clusters

URN to cite this document:: urn:nbn:de:bvb:355-epub-782090
DOI to cite this document:: 10.5283/epub.78209

Schwinghammer, Vanessa F. ; Gärtner, Stefanie

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Date of publication of this fulltext: 25 Nov 2025 07:24

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Abstract

Cs3.4K4.6[Au][Tl7] has been prepared from the elements (Pnma, a = 39.6898(12) Å, b = 12.0407(4) Å, c = 10.9334(3) Å, V = 5225.0(3) Å3, Z = 8, R1/wR2 = 0.0556/0.0935). Band structure calculations reveal a small bandgap at EF (0.10139 eV).

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