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Stable right- and left-handed peptide helices containing Cα-tetrasubstituted α amino acids

Grauer, Andreas ; Cabrele, C. ; Zabel, M. ; König, Burkhard



Abstract

Short peptidomimetics with stable secondary structures in solution are of interest for applications in chemistry, biology, and medicine. One way to rigidify the backbone of a peptide is the use of cyclic Cα-tetrasubstituted α-amino acids (TAAs) like compound 14. The structures resulting from the incorporation of this unnatural amino acid into peptides were investigated. In total, 13 different ...

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