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Monomere Verbindungen der Elemente der 13. und 15. Gruppe

URN to cite this document: urn:nbn:de:bvb:355-opus-9088

Adolf, Ariane (2008) Monomere Verbindungen der Elemente der 13. und 15. Gruppe. PhD, Universität Regensburg

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Abstract (German)

Alle Versuche die wasserstoffsubstituierte Stammverbindung der Phosphanylborane A (A: H2P�BH2) zu synthetisieren, blieben bislang erfolglos. Eine Möglichkeit A zu stabilisieren, und somit eine Kopf-Schwanz-Oligomerisierung zu verhindern, bietet die Koordination einer Lewis-Base (LB) an das Boratom und die Blockierung des freien Elektronenpaares des Phosphoratoms durch Koordination an eine ...


Translation of the abstract (English)

All attempts to synthesise the parent compound H2P-BH2 A of the large class of phosphanylboranes failed, and only theoretical investigations on A have been performed. A possibility to stabilise A and thereby avoid its head-to-tail oligomerisation, is the coordination of a Lewis-base (LB) to the boron atom and a Lewis-acid (LA) to the lone pair of the phosphorusatom to receive LA/LB-stabilised ...


Export bibliographical data

Item Type:Thesis of the University of Regensburg (PhD)
Date:11 December 2008
Referee:Manfred (Prof. Dr.) Scheer
Date of exam:2 November 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:Bor-Phosphor-Verbindungen , Phosphor , Arsen , Lewis-Säure , Lewis-Base , Monomere , Stickstoffgruppe , Borgruppe , 13/15-Verbindungen , Bor-Arsen-Verbindungen , 13/15-compounds , Boron-Arsenic-Compounds
Subjects:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:27 Oct 2009 16:21
Last Modified:13 Mar 2014 11:53
Item ID:10724
Owner Only: item control page


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