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Beiträge zur Chemie verbrückender Pentelidenkomplexe

URN to cite this document: urn:nbn:de:bvb:355-epub-134248

Eisenhut, Christian (2010) Beiträge zur Chemie verbrückender Pentelidenkomplexe. PhD, Universität Regensburg

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Abstract (German)

Im ersten Teil der Arbeit wurde die Darstellung des Phosphinidenkomplexes [Cp*P{Mo(CO)2Cp}2] untersucht. Durch Salzeliminierung aus Cp*PCl2 und Na[Mo(CO)3Cp] wurde der Phosphenkomplex [Cp*(Cl)P{Mo(CO)2Cp}] erzeugt, der durch Reaktionen mit Na[Mo(CO)3Cp] zu [Cp*P{Mo(CO)2Cp}2] regiert. Die durch Hydrolyse resultierende Verbindung [{Mo(CO)2Cp}2(P(OH)Cp*)(H)] wurde durch Röntgenstrukturanalyse ...

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Translation of the abstract (English)

The first part of this thesis explores the preparation of [Cp*P{Mo(CO)2Cp}2] phosphinidene complexes. Through the treatment of Na[Mo(CO)3Cp] with Cp*PCl2 and subsequent elimination of salt the phosphene complex [Cp*(Cl)P{Mo(CO)2Cp}] is realized; further treatment with Na[Mo(CO)3Cp] gives the disubstituted [Cp*P{Mo(CO)2Cp}2] complex. Hydrolysis of [Cp*P{Mo(CO)2Cp}2] results in the ...

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Item Type:Thesis of the University of Regensburg (PhD)
Date:10 September 2010
Referee:Prof. Dr. Manfred Scheer
Date of exam:24 November 2009
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Research groups and research centres:Not selected
Keywords:Phosphor, Phosphiniden, Amine, Hydrolyse, Metallcarbonyle, Aminophosphiniden, Pentylidene Complexes
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:10 Sep 2010 12:34
Last Modified:13 Mar 2014 13:58
Item ID:13424
Owner Only: item control page

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