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Chemistry of Bridging Phosphanes: A Comparative Study within CuI-AgI-AuI Triad-Based Homonuclear Dimers

Welsch, Stefan and Nohra, Brigitte and Peresypkina, Eugenia V. and Lescop, Christian and Scheer, Manfred and Réau, Régis (2009) Chemistry of Bridging Phosphanes: A Comparative Study within CuI-AgI-AuI Triad-Based Homonuclear Dimers. Chemistry - A European Journal 15 (18), pp. 4685-4703.

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Abstract

Bridging ligands in AgI and AuI bimetallic complexes: The P moiety of bis(2-pyridyl)phosphole acts as a symmetrically, semi-, or non-bridging donor in AgI dimers (see figure). In related AuI complexes, only the non-bridging mode is observed. An unsaturated AgI dimer is used as an adaptive molecular clip for the synthesis of -stacked metallocyclophanes. Bis(2-pyridyl)phosphole C reacted with AgPF6 ...

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Item Type:Article
Date:26 March 2009
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.200802115DOI
Keywords:bridging ligands; coordination modes; gold; P ligands; silver
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:18
Last Modified:13 Mar 2014 13:30
Item ID:15099
Owner Only: item control page

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