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N-Heterocyclic Carbenes in Lewis Acid/Base Stabilised Phosphanylboranes

Adolf, Ariane and Vogel, Ulf and Zabel, Manfred and Timoshkin, Alexey Y. and Scheer, Manfred (2008) N-Heterocyclic Carbenes in Lewis Acid/Base Stabilised Phosphanylboranes. European Journal of Inorganic Chemistry 2008 (22), pp. 3482-3492.

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Abstract

The reactions of 2-borane-1,3,4,5-tetramethylimidazoline (BH3·NHCMe) with selected phosphane adducts of the Lewis acids B(C6F5)3 and Ga(C6F5)3 are studied. Among others, adducts (C6F5)3Ga·PH2Cp* (1a) and (C6F5)3B·PH2Cp* (2) are used as starting materials. When the (C6F5)3Ga-phosphane adducts 1a and (C6F5)3Ga·PPhH2 are treated with BH3·NHCMe, the Lewis acid/base stabilised phosphanylboranes ...

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Item Type:Article
Date:4 July 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200800305DOI
Keywords:Boron; Phosphorus; Gallium; Carbenes; Lewis acids; Lewis bases
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:24
Last Modified:13 Mar 2014 13:31
Item ID:15108
Owner Only: item control page
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