Scheer, Manfred and Gregoriades, Laurence John and Merkle, Roger and Johnson, Brian P. and Dielmann, Fabian (2008) Formation of Spherical Giant Molecules and Dynamic Behaviour of Supramolecular Assemblies Based on Pn-Ligand Complexes. Phosphorus, Sulfur and Silicon & the Related Elements 183, pp. 504-508.
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We report herein on our concept of using En-ligand complexes (E = P, As) as linking units for the creation of novel supramolecular ensembles. The reaction of these complexes with Group 11 metal salts of coordinating anions leads to the formation of insoluble oligomers, 1D and 2D polymers as well as soluble spherical nanoscaled clusters. In contrast, the reaction of En-ligand complexes with Group 11 metal salts of weakly coordinating anions yields soluble oligomers and polymers, which display monomer-oligomer equilibria in solution.
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Keywords:||Arsenic; group 11 metals; iron; molybdenum; phosphorus; supramolecular chemistry|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||07 Jun 2010 12:30|
|Last Modified:||07 Jun 2010 12:30|