Deutsch
Welsch, Stefan and Gregoriades, Laurence John and Sierka, Marek and Zabel, Manfred and Virovets, Alexander and Scheer, Manfred (2007) Ungewöhnliches Koordinationsverhalten von Pn-Ligandkomplexen gegenüber Tl+ [Unusual Coordination Behaviour of Pn-Ligand Complexes with Tl+]. Angewandte Chemie 119 (48), pp. 9483-9487.
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Abstract
Pentaphosphaferrocen koordiniert als -Ligand an das große Kation Tl+. Zusätzlich bindet ein Phosphoratom jeder cyclo-P5-Einheit zum benachbarten Tl+-Ion, sodass ein eindimensionales Koordinationspolymer entsteht. In Lösung und im Festkörper wird auch bei tiefen Temperaturen eine schnelle Rotation der P5-Ringe beobachtet.
| Item Type: | Article | ||||
|---|---|---|---|---|---|
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
| ||||
| Keywords: | Wechselwirkungen; Koordinationspolymere; Phosphor; Schwach koordinierende Anionen; Thallium | ||||
| Subjects: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Owner: | Martin Kaiser | ||||
| Deposited On: | 07 Jun 2010 14:31 | ||||
| Last Modified: | 21 Jul 2011 00:29 | ||||
| Item ID: | 15130 |
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