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- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.15143
Zusammenfassung
Not as innocent as it looks: Reaction of the phosphinidene complex 1 with tBuCP leads, via a WP triply bound intermediate, to the diphosphabutenonyl ligand complex 2, whereas the reaction with MesCP (Mes=2,4,6-Me3C6H2) leads, through an unprecedented ring opening of the innocent Cp* ligand (Cp*=C5Me5) and insertion of the phosphaalkyne and the phosphinidene P atom, to the novel diphosphacyclooctatetraene ligand complex 3.
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