Startseite UB

Ring Expansion of a Cp* Moiety: Formation of a 1,2-Diphosphacyclooctatetraene Ligand [Ringerweiterung einer Cp*-Einheit - Bildung eines 1,2-Diphosphacyclooctatetraen-Liganden]

Scheer, Manfred and Himmel, Daniel and Johnson, Brian P. and Kuntz, Christian and Schiffer, Michael (2007) Ring Expansion of a Cp* Moiety: Formation of a 1,2-Diphosphacyclooctatetraene Ligand [Ringerweiterung einer Cp*-Einheit - Bildung eines 1,2-Diphosphacyclooctatetraen-Liganden]. Angewandte Chemie International Edition 46 (21), pp. 3971-3975.

[img]PDF
Download (181kB) - Repository staff only

at publisher (via DOI)


Abstract

Not as innocent as it looks: Reaction of the phosphinidene complex 1 with tBuCP leads, via a WP triply bound intermediate, to the diphosphabutenonyl ligand complex 2, whereas the reaction with MesCP (Mes=2,4,6-Me3C6H2) leads, through an unprecedented ring opening of the innocent Cp* ligand (Cp*=C5Me5) and insertion of the phosphaalkyne and the phosphinidene P atom, to the novel ...

plus


Export bibliographical data



Item Type:Article
Date:10 April 2007
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.200605173DOI
Keywords:density functional calculations, phosphaalkynes, phosphinidene complexes, phosphorus, tungsten
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:39
Last Modified:13 Mar 2014 13:32
Item ID:15143
Owner Only: item control page

Downloads

Downloads per month over past year

  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact