Balázs, Gábor and Gregoriades, Laurence John and Scheer, Manfred (2007) Triple Bonds between Transition Metals and the Heavier Elements of Groups 14 and 15. Organometallics 26 (13), pp. 3058-3075.
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In the mid-1990s, the first examples of complexes containing triple bonds between transition metals and heavier analogues of the carbon as well as the nitrogen groups were reported, thus signaling the beginning of a new era in organometallic chemistry. Since then the progress in this field has been tremendous, with a large number of representative complexes being isolated and characterized. This review highlights the astonishing development of the chemistry of complexes containing triple bonds between transition metals and the heavier elements of groups 14 and 15 since its birth. The synthesis and the structural and spectroscopic features of these compounds are comprehensively discussed. Furthermore, the elucidation of their bonding modes by quantum-chemical methods as well as the relation between the reactivities of these complexes and their electronic structures are presented.
|Date:||23 May 2007|
|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||07 Jun 2010 12:40|
|Last Modified:||20 Jul 2011 22:29|