Startseite UB

Lewis Base Stabilized Phosphanylborane

Schwan, Karl-Christian and Timoshkin, Alexey Y. and Zabel, Manfred and Scheer, Manfred (2006) Lewis Base Stabilized Phosphanylborane. Chemistry - A European Journal 12 (18), pp. 4900-4908.

[img]PDF
Download (364kB) - Repository staff only

at publisher (via DOI)


Abstract

The abstraction of the Lewis acid from [W(CO)5(PH2BH2NMe3)] (1) by an excess of P(OMe3)3 leads to the quantitative formation of the first Lewis base stabilized monomeric parent compound of phosphanylborane [H2PBH2NMe3] 2. Density functional theory (DFT) calculations have shown a low energetic difference between the crystallographically determined antiperiplanar arrangement of the lone pair and ...

plus


Export bibliographical data

Item Type:Article
Date:27 April 2006
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.200600185DOI
Keywords:boron; density functional calculations; Lewis bases; phosphorus
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:07 Jun 2010 12:59
Last Modified:13 Mar 2014 13:33
Item ID:15206
Owner Only: item control page
  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact