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Reactivity of a Phosphanylalane Complex towards Lewis Bases

Vogel, Ulf and Schwan, Karl-Christian and Scheer, Manfred (2004) Reactivity of a Phosphanylalane Complex towards Lewis Bases. European Journal of Inorganic Chemistry 2004 (10), pp. 2062-2065.

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Abstract

The reactivity of the Lewis acid/base stabilized complex of phosphanylalane [(CO)5W(H2PAlH2·NMe3)] (1) towards the Lewis bases THF and NMe3 has been investigated. The reaction with THF leads to decomposition of the complex. One of the decomposition products was identified as containing the anion [{(CO)5W}2PH2]- (2). This anion could be synthesized independently by reaction of [(CO)5WPH3] with KH ...

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Item Type:Article
Date:5 March 2004
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.200300637DOI
Keywords:Aluminum; Phosphorus; Hydrides; Reactivity; Lewis bases
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:11
Last Modified:13 Mar 2014 13:34
Item ID:15231
Owner Only: item control page

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