Startseite UB

First Examples of Electrophilic Addition to a Fe2Q Face of [Fe3(μ3-Q)(CO)9]2− (Q=Se, Te)—Synthesis and Characterisation of [MFe3(μ4-Q)(CO)9Cp*] and [IrFe2(μ3-Q)(CO)7Cp*] (M=Rh, Ir; Cp*=η5-C5(CH3)5)

Konchenko, Sergei N. and Pushkarevsky, Nikolai A. and Scheer, Manfred (2003) First Examples of Electrophilic Addition to a Fe2Q Face of [Fe3(μ3-Q)(CO)9]2− (Q=Se, Te)—Synthesis and Characterisation of [MFe3(μ4-Q)(CO)9Cp*] and [IrFe2(μ3-Q)(CO)7Cp*] (M=Rh, Ir; Cp*=η5-C5(CH3)5). Journal of Cluster Science 14 (3), pp. 299-312.

[img]PDF
Download (239kB) - Repository staff only

at publisher (via DOI)


Abstract

The reaction of [Et4N]2[Fe3(mgr 3-Q)(CO)9] (Q=Se ([Et4N]2[1b]), Te ([Et4N]2[1c])) with [Cp*M(CH3CN)3][CF3SO3]2 (M=Rh, Ir) leads to the addition of a Cp*M2+ unit to a Fe2Q face of the initial cluster. In this way four new heteronuclear clusters [MFe3(mgr 4-Q)(CO)9Cp*] (M=Rh (2b, c); M=Ir (3b, c)) were obtained possessing a butterfly-shaped cluster core bridged by a mgr 4-Q unit. Furthermore, ...

plus


Export bibliographical data

Item Type:Article
Date:25 October 2003
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1023/B:JOCL.0000005065.76523.69DOI
Keywords:Cluster; carbonyl complexes; iron; rhodium; iridium; selenium; tellurium
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:14 Jun 2010 12:13
Last Modified:13 Mar 2014 13:34
Item ID:15235
Owner Only: item control page
  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact