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Structure and reactivity of transition metal substituted dichloroantimony and dichlorobismuth complexes

Gröer, Thomas and Scheer, Manfred (2000) Structure and reactivity of transition metal substituted dichloroantimony and dichlorobismuth complexes. Journal of the Chemical Society, Dalton Transactions 2000 (5), pp. 647-653.

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Abstract

The dichloro Group 15 complexes [{Cpx(CO)2Fe}BiCl2] (Cpx = Cp, 5-C5H3tBu2{Cp}) 1a, b and [{Cp(CO)2Fe}SbCl2] 3 are prepared. The crystal structure determination of 1b and 3 shows a polymeric chlorine bridged structure for the bismuth complex 1b whereas for the antimony compound 3 a molecular structure with weak intermolecular chlorine bridges is found. The reaction of 1a or 3 with magnesium leads ...

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Item Type:Article
Date:2000
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/a909394jDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:21 Jun 2010 12:37
Last Modified:13 Mar 2014 13:38
Item ID:15471
Owner Only: item control page
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