Complexes Containing Phosphorus and Arsenic as Terminal Ligands [Komplexe mit Phosphor und Arsen als terminalen Liganden} [brace not closed]

Abstract

Complexes with terminal pnictide ligands are interesting in themselves and as ligands for the complexation of Lewis acids. Herein the syntheses of complexes such as 1 (E P, As) and 2 (M Cr, W) are described, and detailed theoretical studies on the relative thermodynamic stability of these and analogously constructed complexes are presented.