Budzichowski, Theodore A. and Chisholm, Malcolm H. and Folting, Kirsten and Streib, William E. and Scheer, Manfred (1996) Tetranuclear Phosphinidine, Phosphide, Arsenide, and Oxide Anionic Clusters of Molybdenum and Tungsten Supported by Neopentoxide Ligands: Na(18-crown-6)[M4(μ3-PSiMe3)(OCH2tBu)11], K(18-crown-6)[M4(μ3-E)(OCH2tBu)10] (E = P, As), K(18-crown-6)2[Mo4(μ3-O)(OCH2tBu)11]. Inorganic Chemistry 35 (12), pp. 3659-3666.
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From the reactions between M2(OCH2tBu)6 (2 equiv) and NaP(SiMe3)2 (1 equiv) in benzene and 18-crown-6 the phosphinidine clusters [M4(μ3-PSiMe3)(OCH2tBu)11]-, compounds 1 (M = Mo) and 2 (M = W) are formed and are reactive intermediates in the formation of [M4(μ3-P)(OCH2tBu)10]- cluster anions, compounds 3 (M = Mo) and 4 (M = W), respectively, which have been isolated and characterized as their ...
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|Institutions:||Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Created at the University of Regensburg:||Unknown|
|Deposited On:||21 Jun 2010 12:49|
|Last Modified:||13 Mar 2014 13:40|