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Reactions of [Fe3(µ3-Q)(CO)9]2–(Q = Se, Te) with organic and organometallic dihalides of group 15 elements – an approach to functionalised clusters

Konchenko, Sergei N. and Pushkarevsky, Nikolai A. and Virovets, Alexander V. and Scheer, Manfred (2003) Reactions of [Fe3(µ3-Q)(CO)9]2–(Q = Se, Te) with organic and organometallic dihalides of group 15 elements – an approach to functionalised clusters. Dalton Transactions 2003 (6), pp. 581-585.

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Abstract

A number of novel nido-clusters of the type [Fe3(µ3-SbR)(µ3-Q)(CO)9] containing the heavier group 16 elements (Q = Se, Te) and Sb as group 15 element with attached functional groups (R = Cp*, (5-C5H4tBu)Fe(CO)2) have been obtained by the reaction of K2[Fe3(µ3-Q)(CO)9](Q = Se, Te) with RSbX2(X = Br, I). Furthermore, a first cluster [Fe3(µ3-BiFe(CO)2(5-C5H4tBu))(µ3-Se)(CO)9] containing a Bi/Se ...

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Item Type:Article
Date:23 January 2003
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/b210839aDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Owner: Martin Kaiser
Deposited On:19 Jul 2010 12:25
Last Modified:13 Mar 2014 13:53
Item ID:15948
Owner Only: item control page
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