Startseite UB

Dimerization of pentanuclear clusters [Fe3Q(AsMe)(CO)9] (Q = Se, Te) as conversion pathway to novel cubane-like aggregates

Pushkarevsky, Nikolai A. and Konchenko, Sergei N. and Zabel, Manfred and Bodensteiner, Michael and Scheer, Manfred (2011) Dimerization of pentanuclear clusters [Fe3Q(AsMe)(CO)9] (Q = Se, Te) as conversion pathway to novel cubane-like aggregates. Dalton Transactions 40 (9), pp. 2067-2074.

Full text not available from this repository.

at publisher (via DOI)

Other URL: http://pubs.rsc.org/en/Content/ArticlePDF/2011/DT/C0DT01587C


Abstract

The first examples of carbonyl heterocubane-type clusters, [Fe4(μ3-Q)2(μ3-AsMe)2(CO)12] (2, Q = Se (a), Te (b)), which simultaneously contain elements of group 15 and 16, were obtained by thermolysis of [Fe3(μ3-Q)(μ3-AsMe)(CO)9] (1) in acetonitrile. The clusters 2 possess a cubic Fe4Q2As2 core with alternating Fe and Q/As atoms. The coordination environment of the Fe atoms is close to octahedral, ...

plus


Export bibliographical data

Item Type:Article
Date:7 March 2011
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/C0DT01587CDOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Andreas Stauber
Deposited On:24 Feb 2011 14:22
Last Modified:24 Feb 2011 14:22
Item ID:19887
Owner Only: item control page
  1. University

University Library

Publication Server

Contact person
Gernot Deinzer

Telefon 0941 943-2759
Contact