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Reaktivitätsuntersuchungen an verbrückenden Pentelidenkomplexen

Kuntz, Christian (2009) Reaktivitätsuntersuchungen an verbrückenden Pentelidenkomplexen. PhD, Universität Regensburg.

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Date of publication of this fulltext: 27 Mar 2009 15:24

Abstract (German)

Im ersten Teil der vorliegenden Arbeit wurde die Reaktivität der Pentelidenkomplexe [Cp*E{W(CO)5}2] (E = P, As) gegenüber nucleophilen Reagenzien wie z. B. Phosphanen (PR3, R = H, organischer Rest) untersucht. Die Reaktion der Pentelidenkomplexe [Cp*E{W(CO)5}2] mit primären Phosphanen (RPH2, R = BH2NMe3, organischer Rest) lieferte in Abhängigkeit des sterischen Anspruchs des organischen Restes ...


Translation of the abstract (English)

In the first part of the thesis, the reactivity of the pentelidene-complexes [Cp*E{W(CO)5}2] (E = P, As) is tested against nucleophilic reagents e.g. phosphanes PR3 (R = H, organic group). Depending on the sterical demand of the organic group, the reaction of [Cp*E{W(CO)5}2] with primary phosphanes (RPH2, R = BH2NMe3, organic group) leads to the formation of Lewis-acid/base-adducts of the type ...


Export bibliographical data

Item type:Thesis of the University of Regensburg (PhD)
Date:26 March 2009
Referee:Manfred (Prof. Dr.) Scheer
Date of exam:28 February 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:Phosphor , Arsenide , Kohlenstoff , Metallcarbonyle , Phosphiniden , Wolframkomplexe , Phosphane , Pyrolyse , Photolyse , Pnictide , Arsiniden , phosphorus , arsenic , carbon , tungsten , phosphinidene
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:12121
Owner only: item control page


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