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Chemistry of Bridging Phosphanes: A Comparative Study within CuI-AgI-AuI Triad-Based Homonuclear Dimers

Welsch, Stefan ; Nohra, Brigitte ; Peresypkina, Eugenia V. ; Lescop, Christian ; Scheer, Manfred ; Réau, Régis
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Date of publication of this fulltext: 07 Jun 2010 12:18


Abstract

Bridging ligands in AgI and AuI bimetallic complexes: The P moiety of bis(2-pyridyl)phosphole acts as a symmetrically, semi-, or non-bridging donor in AgI dimers (see figure). In related AuI complexes, only the non-bridging mode is observed. An unsaturated AgI dimer is used as an adaptive molecular clip for the synthesis of -stacked metallocyclophanes. Bis(2-pyridyl)phosphole C reacted with AgPF6 ...

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