Chemistry of Bridging Phosphanes: A Comparative Study within CuI-AgI-AuI Triad-Based Homonuclear Dimers

DOI to cite this document:: 10.5283/epub.15099

Welsch, Stefan ; Nohra, Brigitte ; Peresypkina, Eugenia V.

; Lescop, Christian ; Scheer, Manfred

; Réau, Régis

PDF
(1MB) - Repository staff only

Date of publication of this fulltext: 07 Jun 2010 12:18

Alternative links to fulltext:DOI

Details

Indexed in

Export bibliographical data

Abstract

Bis(2-pyridyl)phosphole C reacted with AgPF6 and dppm giving rise to dicationic dimer 1. in which C acts as a 1 kappa N:1,2 kappa P:2 kappa N-donor with a symmetrically bridging P-centre. This complex gives the first example of dimers based on trigonal planar metal centres bearing a bridging sigma(3),lambda(3)-phosphane ligand. The reaction of two equivalents of C with AgPF6 and ...