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N-Heterocyclic Carbenes in Lewis Acid/Base Stabilised Phosphanylboranes

Adolf, Ariane ; Vogel, Ulf ; Zabel, Manfred ; Timoshkin, Alexey Y. ; Scheer, Manfred
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Date of publication of this fulltext: 07 Jun 2010 12:24


Abstract

The reactions of 2-borane-1,3,4,5-tetramethylimidazoline (BH3·NHCMe) with selected phosphane adducts of the Lewis acids B(C6F5)3 and Ga(C6F5)3 are studied. Among others, adducts (C6F5)3Ga·PH2Cp* (1a) and (C6F5)3B·PH2Cp* (2) are used as starting materials. When the (C6F5)3Ga-phosphane adducts 1a and (C6F5)3Ga·PPhH2 are treated with BH3·NHCMe, the Lewis acid/base stabilised phosphanylboranes ...

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