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N-Heterocyclic Carbenes in Lewis Acid/Base Stabilised Phosphanylboranes

Adolf, Ariane, Vogel, Ulf, Zabel, Manfred, Timoshkin, Alexey Y. and Scheer, Manfred (2008) N-Heterocyclic Carbenes in Lewis Acid/Base Stabilised Phosphanylboranes. European Journal of Inorganic Chemistry 2008 (22), pp. 3482-3492.

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The reactions of 2-borane-1,3,4,5-tetramethylimidazoline (BH3·NHCMe) with selected phosphane adducts of the Lewis acids B(C6F5)3 and Ga(C6F5)3 are studied. Among others, adducts (C6F5)3Ga·PH2Cp* (1a) and (C6F5)3B·PH2Cp* (2) are used as starting materials. When the (C6F5)3Ga-phosphane adducts 1a and (C6F5)3Ga·PPhH2 are treated with BH3·NHCMe, the Lewis acid/base stabilised phosphanylboranes ...


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Item type:Article
Date:4 July 2008
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Boron; Phosphorus; Gallium; Carbenes; Lewis acids; Lewis bases
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15108
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