Fullerene-Like Nanoballs Formed by Pentaphosphaferrocene and CuBr

DOI zum Zitieren dieses Dokuments:: 10.5283/epub.15211

Scheer, Manfred ; Bai, Junfeng ; Johnson, Brian P. ; Merkle, Roger ; Virovets, Alexander ; Anson, Christopher E.

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Veröffentlichungsdatum dieses Volltextes: 07 Jun 2010 13:04

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Zusammenfassung

Reaction of [CpxFe(5-P5)] {Cpx = 5-C5Me5 (1a), 5-C5Me4Et (1b)} with CuBr leads to the fullerene-like nanoballs [{CpxFe(5:1:1:1:1:1-P5)}12{CuBr}10{Cu2Br3}5{Cu(CH3CN)2}5] {Cpx = 5-C5Me5 (5a), 5-C5Me4Et (5b)} comprising a cluster core of 90 non-carbon atoms. In contrast to previous results by variation of stoichiometry and concentration conditions, the formation of polymeric product was hindered, ...