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Reactivity of a Phosphanylalane Complex towards Lewis Bases

Vogel, Ulf, Schwan, Karl-Christian and Scheer, Manfred (2004) Reactivity of a Phosphanylalane Complex towards Lewis Bases. European Journal of Inorganic Chemistry 2004 (10), pp. 2062-2065.

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The reactivity of the Lewis acid/base stabilized complex of phosphanylalane [(CO)5W(H2PAlH2·NMe3)] (1) towards the Lewis bases THF and NMe3 has been investigated. The reaction with THF leads to decomposition of the complex. One of the decomposition products was identified as containing the anion [{(CO)5W}2PH2]- (2). This anion could be synthesized independently by reaction of [(CO)5WPH3] with KH ...


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Item type:Article
Date:5 March 2004
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Aluminum; Phosphorus; Hydrides; Reactivity; Lewis bases
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15231
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