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Synthesis of Novel Transition Metal-Group 15 Cage Compounds and their Use as Molecular Precursors for Binary and Ternary Transition Metal Pnictides

Vogel, Ulf ; Scheer, Manfred


The reaction of [lcubW(CO)5rcub2PCl] with K[Co(CO)4] yields the novel compounds [W(CO)4(η4-#12296Co(CO)3PlcubW(CO)5rcub#122972)[ (1) and [lcub(CO)4WCo3(CO)6rcub(μ3-PlcubW(CO)5rcub)] (2) along with the previously known derivatives [Co2(CO)6(μ,η2-P2lcubW(CO)5rcub2)] (3) and [Co3(CO)9(μ3-PlcubW(CO)5rcub)] (4). Complex [W2(CO)8(μ-CO)(μ,η2-P2lcubW(CO)5rcub2) (5) was synthesised by reacting ...


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