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An Approach to Novel Complexes with a Tungsten−Phosphorus Triple Bond

Scheer, Manfred, Kramkowski, Peter and Schuster, Kay (1999) An Approach to Novel Complexes with a Tungsten−Phosphorus Triple Bond. Organometallics 18 (15), pp. 2874-2883.

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The metathesis reaction of [W2(OtBu)6] with tBuCP leads to the phosphido complex [(tBuO)3WP] (1), which can be stabilized when the reaction is carried out in the presence of Lewis acidic carbonyl complexes of the type [M(CO)5thf] (M = Cr, W). However, further reaction of the metathesis products [(tBuO)3WCtBu] and [(tBuO)3WP→M(CO)5] [M = W (4a), Cr (4b)] with tBuCP leads after subsequent 1,3-OtBu ...


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Item type:Article
Date:19 July 1999
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15476
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