Different Ways of P4 Transformation in the Coordination Sphere of Transition Metals

DOI zum Zitieren dieses Dokuments:: 10.5283/epub.15495

Scheer, Manfred ; Schuster, Kay ; Becker, Uta

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Veröffentlichungsdatum dieses Volltextes: 21 Jun 2010 12:49

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The transformation pathway of tetrahedral P4 to the corresponding Pn ligands has been studied by the three-component-reaction are found to depend on the electron number of the complex fragments used. In the case of complexes forming fragments with an even number of valence electrons, a stepwise P-P bond cleavage is observed with a bicyclotetraphosphine intermediate to give a cyclo-P4 containing ...