3-Phenylisochromans and 2-Phenylbenzofurans from 1-Benzyltetrahydroisoquinolines: Tertiary Alcohol- and Phenol-Groups as Nucleophiles

URN to cite this document:: urn:nbn:de:bvb:355-epub-156127
DOI to cite this document:: 10.5283/epub.15612

Ambros, R. ; Prior, S. ; Wiegrebe, Wolfgang

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Date of publication of this fulltext: 01 Jul 2010 08:47

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Item type:	Article
Journal or Publication Title:	Scientia Pharmaceutica
Volume:	51
Number of Issue or Book Chapter:	2
Page Range:	pp. 179-183
Date:	1983
Institutions:	Chemistry and Pharmacy > Institute of Pharmacy > Alumni or Retired Professors > Prof. Wiegrebe
Keywords:	Ethyl chloroformate, 3-phenylisochromans, 2-phenylbenzofurans, intramolecular nucleophilic substitution
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Unknown
Item ID:	15612

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Abstract

Ethyl chloroformate (ECF) and the 1-benzyl-tetrahydroisoquinoline with a a-hydroxy-amethylethyl- group at C-2' 5 react to a 1,1-dimethyl-3-phenylisochroman 6. Under identical conditions the C-2'-OH-substituted 1-benzyl-tetrahydroisoquinoline 7 affords the stilbene 13 and a 2-phenylbenzofuran 14. Chlorameisensäureethylester und das 1-Benzyl-tetrahydroisochinolin mit einer ...

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