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3-Phenylisochromans and 2-Phenylbenzofurans from 1-Benzyltetrahydroisoquinolines: Tertiary Alcohol- and Phenol-Groups as Nucleophiles

URN to cite this document:
urn:nbn:de:bvb:355-epub-156127
Ambros, R. ; Prior, S. ; Wiegrebe, Wolfgang
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Date of publication of this fulltext: 01 Jul 2010 08:47


Abstract

Ethyl chloroformate (ECF) and the 1-benzyl-tetrahydroisoquinoline with a a-hydroxy-amethylethyl- group at C-2' 5 react to a 1,1-dimethyl-3-phenylisochroman 6. Under identical conditions the C-2'-OH-substituted 1-benzyl-tetrahydroisoquinoline 7 affords the stilbene 13 and a 2-phenylbenzofuran 14. Chlorameisensäureethylester und das 1-Benzyl-tetrahydroisochinolin mit einer ...

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