Go to content
UR Home

Bishydrocotarnines - Stereochemical Aspects

URN to cite this document:
urn:nbn:de:bvb:355-epub-156629
DOI to cite this document:
10.5283/epub.15662
Okamoto, Y. ; Dirnberger, D. ; Burgemeister, T. ; Dannhardt, G. ; Wiegrebe, Wolfgang
[img]
Preview
PDF
(860kB)
Date of publication of this fulltext: 07 Jul 2010 05:03


Abstract

The bishydrocotarnines 2a and 2b1)' **) were converted into the urethanes 9a and 9b and into the carbamates 10a and 10b, which in turn were split to yield the sec. amines 11a and 11b. Cyclisation with diethyl oxalate led to the diketopiperazines 12a and 12b. Contrary to 9b, compound 9a was resolved into enantiomers on a cellulose carbamate column. This indicates that 9a is the D, L- and 9b is the ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons