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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-156736
- DOI to cite this document:
- 10.5283/epub.15673
Abstract
Enantioselective hydrosilylations of the 3,4-dihydropyrrole derivatives 1a-c and 5 with in-situ catalysts consisting of [Rh(cod)Cl]2 and optically active phosphines yield the N-silyl compounds 2a-c and 6 in up to 66.1 % ee. The N-silyl derivatives were treated with acetic formic anhydride or trifluoroacetic anhydride to give the N-formyl and N-trifluoroacetyl compounds 3a-c, 4a-c, 7, and 8. The ...
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