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Enantioselective Synthesis of Some Nicotiana Alkaloids

Mahboobi, Siavosh and Wiegrebe, Wolfgang (1988) Enantioselective Synthesis of Some Nicotiana Alkaloids. Archiv der Pharmazie 321, pp. 175-177.

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Abstract

A modified approach to myosmine (6) via a silyl enol ether of 3-acetylpyridine (1) is described. Chiral reduction of 6 with N-(benzyloxycarbonyl)-Lproline/ NaBH4 and formylation leads to (R)-N-formylnornicotine (8) (35 % ee) which in turn is converted to (R)-nornicotine (11) and R-nicotine (10). Wir beschreiben eine modifizierte Synthese des Myosmins (6) über einen Silylenolether des ...

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Item type:Article
Date:1988
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Alumni or Retired Professors > Prof. Wiegrebe
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Item ID:15687
Owner only: item control page

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