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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-156874
- DOI to cite this document:
- 10.5283/epub.15687
Abstract
A modified approach to myosmine (6) via a silyl enol ether of 3-acetylpyridine (1) is described. Chiral reduction of 6 with N-(benzyloxycarbonyl)-Lproline/ NaBH4 and formylation leads to (R)-N-formylnornicotine (8) (35 % ee) which in turn is converted to (R)-nornicotine (11) and R-nicotine (10). Wir beschreiben eine modifizierte Synthese des Myosmins (6) über einen Silylenolether des ...
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