Go to content
UR Home

Degradation of 1-Benzyl-1,2,3,4-tetrahydroisoquinolines (Laudanosine) with Ethyl chloroformate: Gedamer's Intermediate

URN to cite this document:
urn:nbn:de:bvb:355-epub-156947
Angerer, S. von ; Eibler, E. ; Lee, D.-U. ; Wiegrebe, Wolfgang
[img]
Preview
PDF
(533kB)
Date of publication of this fulltext: 08 Jul 2010 04:45


Abstract

Gadamer has postulated the α-chlorobisbenzyl derivate 2a as an intermediate of the degradation of laudanosine [(-)-1] to the stilbene 3 by ethyl chloroformate. Optically active 2a is easily hydrolyzed to the corresponding carbinol 2b. The optical purity of 2b is determined via diastereomeric esters. Als Zwischenprodukt des Chlorameisensäureethylester-Abbaus von Laudanosin [(-)-)1] zum Stilben 3 ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons