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Removal of the Pyrrolidine Substituent by Dehydrogenation of 4-Pyrrolidin-2-yl-3,4-dihydro- and 1,2,3,4-tetrahydroisoquinolines

URN to cite this document:
urn:nbn:de:bvb:355-epub-157952
DOI to cite this document:
10.5283/epub.15795
Mahboobi, Siavosh ; Karcher, A. ; Grothus, Götz ; Wagner, W. ; Wiegrebe, Wolfgang
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Date of publication of this fulltext: 12 Jul 2010 09:42


Abstract

Pyrrolidin-2-yl-groups located at C-4 of 3,4-dihydro- or 1,2,3,4-tetrahydroisoquinolines, respectively, are lost in the course of dehydrogenation of these isoquinoline derivatives. However, acyclically substituted isoquinolines, hydrogenated in ring B, 2-benzyl-4-(l-dimethylaminoethyl)-l,2,3,4- tetrahydroisoquinoline, e.g., show loss of the amine group only by benzylic cleavage, affording ...

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