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Reduction of Nitroxides by Anthralin and some of its Derivatives

Pecar, S. ; Schara, M. ; Müller, K. ; Wiegrebe, Wolfgang



Abstract

In DMSO solution, anthralin and its C-10 monosubstituted derivatives reduce nitroxides to the corresponding hydroxylamine derivatives, which are not further transformed. The reaction rate depends on the solvent used, the nitroxide, and the structure of the reducer. It is faster in DMSO than in DMF, piperidine type of nitroxides are reduced faster than the pyrrolidine type, and the substitution on ...

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