Go to content
UR Home

Different Transformation Pathways in the Photolysis of [Cp*P{W(CO)5}2]

Schiffer, Michael ; Leiner, Eva ; Scheer, Manfred
[img]PDF
(257kB) - Repository staff only
Date of publication of this fulltext: 19 Jul 2010 12:26


Abstract

Photolysis of [Cp*P{W(CO)5}2] (1) leads to the novel complex [{Cp*(CO)6W2}(µ-H)(-1:1:1-P2){W(CO)5}2] (4), which was structurally and spectroscopically characterised. The product is formed by a Cp* migration within 1 to give the phosphido complex intermediate [Cp*(CO)2WPW(CO)5], as well as by a Cp* elimination to form an intermediate of the type [P{W(CO)5}2], both of which dimerise to yield product 4.


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons