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Different Transformation Pathways in the Photolysis of [Cp*P{W(CO)5}2]

Schiffer, Michael, Leiner, Eva and Scheer, Manfred (2001) Different Transformation Pathways in the Photolysis of [Cp*P{W(CO)5}2]. European Journal of Inorganic Chemistry 2001 (7), pp. 1661-1663.

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Photolysis of [Cp*P{W(CO)5}2] (1) leads to the novel complex [{Cp*(CO)6W2}(µ-H)(-1:1:1-P2){W(CO)5}2] (4), which was structurally and spectroscopically characterised. The product is formed by a Cp* migration within 1 to give the phosphido complex intermediate [Cp*(CO)2WPW(CO)5], as well as by a Cp* elimination to form an intermediate of the type [P{W(CO)5}2], both of which dimerise to yield product 4.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Photolysis; Cyclopentadienyl ligands; Tungsten; P ligands
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15949
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